Organoamine-Directed Assembly of 5p-4f Heterometallic Cluster Substituted Polyoxometalates: Luminescence and Proton Conduction Properties.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02099
Abstract: The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p-4f heterometallic cluster substituted POMs were successfully isolated by a facile one-step… read more here.
Keywords: heterometallic cluster; substituted polyoxometalates; chemistry; assembly heterometallic ... See more keywords
Two rare Cr–Ln (Ln = Dy, Tb) heterometallic cluster substituted polyoxometalates featuring hexameric aggregates: hydrothermal syntheses, crystal structures and magnetic studies
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c8nj06327c
Abstract: Two hexameric Cr–Ln cluster substituted POMs have been obtained under hydrothermal conditions. They represent the first examples of 3d–4f heterometallic cluster substituted POMs incorporating Cr–Ln clusters. read more here.
Keywords: rare heterometallic; heterometallic cluster; cluster; substituted polyoxometalates ... See more keywords
Fabrication of Metal-Substituted Polyoxometalates for Colorimetric Detection of Dopamine and Ractopamine
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DOI: 10.3390/ma11050674
Abstract: A novel colorimetric detection method based on the peroxidase-like activity of metal-substituted polyoxometalates (POMs) of SiW9M3 (M = Co2+, Fe3+, Cu2+, Mn2+) has been established. POMs can catalyze oxidation of dopamine (DA) and ractopamine (RAC)… read more here.
Keywords: metal substituted; colorimetric detection; detection; substituted polyoxometalates ... See more keywords
Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27248799
Abstract: Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional… read more here.
Keywords: polyoxometalates structural; advances substituted; substituted polyoxometalates; recent advances ... See more keywords