A Redox-Relay Heck Approach to Substituted Tetrahydrofurans
Sign Up to like & getrecommendations! Published in 2023 at "Organic Letters"
DOI: 10.1021/acs.orglett.3c00769
Abstract: An operationally simple and efficient strategy for the synthesis of substituted tetrahydrofurans from readily available cis-butene-1,4-diol is described. A redox-relay Heck reaction is used to rapidly access cyclic hemiacetals that can be directly reduced to… read more here.
Keywords: redox relay; heck approach; substituted tetrahydrofurans; relay heck ... See more keywords
Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06521e
Abstract: Understanding the influence of emerging fluorinated motifs is of a crucial importance in the context of the exponentially growing exploitation of fluorine in many fields. Herein, we report on the dramatic effect of a local… read more here.
Keywords: substituted tetrahydrofurans; cf3 substituted; oxocarbenium ions; highly substituted ... See more keywords