Substitution lability of the perfluorinated Cp* ligand in Rh(I) complexes.
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DOI: 10.1039/d3dt00425b
Abstract: Several cationic rhodium(I) complexes [Rh(COD)L2][C5(CF3)5] have been synthesized through substitution of the weakly bound [C5(CF3)5]- ligand from [Rh(COD)(C5(CF3)5)], further emphasizing its unique reactivity. Besides acetonitrile, pyridine derivatives with varying degrees of fluorination have been employed… read more here.
Keywords: lability perfluorinated; ligand complexes; substitution lability; ligand ... See more keywords