Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus
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DOI: 10.1039/d2sc02496a
Abstract: We report a diversification strategy that enables the direct substituent exchange of tertiary phosphines. Alkylated phosphonium salts, prepared by standard alkylation of phosphines, are selectively dearylated in a nickel-catalysed process to access alkylphosphine products via… read more here.
Keywords: nickel catalysed; substitution phosphorus; diversification; formal substitution ... See more keywords