Calcium Bistriflimide-Mediated Sulfur(VI)–Fluoride Exchange (SuFEx): Mechanistic Insights toward Instigating Catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01230
Abstract: We report a mechanistic investigation of calcium bistriflimide-mediated sulfur(VI)–fluoride exchange (SuFEx) between sulfonyl fluorides and amines. We determine the likely pre-activation resting state—a calcium bistriflimide complex with ligated amines—thus allowing for corroborated calculation of the… read more here.
Keywords: calcium; sufex; bistriflimide mediated; mediated sulfur ... See more keywords
Advances in the construction of diverse SuFEx linkers
Sign Up to like & getrecommendations! Published in 2023 at "National Science Review"
DOI: 10.1093/nsr/nwad123
Abstract: Sulfur fluoride exchange (SuFEx), a new generation of click chemistry, was first presented by Sharpless, Dong, and coworkers in 2014. Owing to the high stability and yet efficient reactivity of the SVI-F bond, SuFEx has… read more here.
Keywords: sufex; sufex linkers; chemistry; construction diverse ... See more keywords