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Published in 2019 at "Nature catalysis"
DOI: 10.1038/s41929-019-0382-8
Abstract: The C-branched pentose sugar d-apiose is important for plant cell wall development. Its biosynthesis as urdine diphosphate-d-apiose (UDP-d-apiose) involves decarboxylation of the UDP-d-glucuronic acid precursor coupled with pyranosyl-to-furanosyl sugar ring contraction. This unusual multistep reaction…
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Keywords:
sugar ring;
biosynthesis;
udp apiose;
ring contraction ... See more keywords
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Published in 2019 at "Journal of Sulfur Chemistry"
DOI: 10.1080/17415993.2019.1616734
Abstract: Thiosugars containing a sulfur atom as heteroatom in the sugar ring are highly interesting. In particular, 5-thioaldopyranoses have attracted considerable attention because they exhibit biologically important properties as the substrates for glycosidases also can be…
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Keywords:
nmr data;
sulfur atom;
sugar ring;
chemistry ... See more keywords