The method for synthesis of 2-sulfanyl closo-decaborate anion and its S-alkyl and S-acyl derivatives
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DOI: 10.1016/j.jorganchem.2016.11.035
Abstract: Abstract A two-stage method for preparation of the sulfanyl derivative of closo-decaborate anion (n-Bu4N)2[2-B10H9SH]2- (1) is worked out. At the first stage, the [2-B10H9SC(NMe2)2]- (2) or the [2-B10H9SCHNMe2]- (3) derivative is obtained by the reaction… read more here.
Keywords: decaborate anion; closo decaborate; sulfanyl;
Condensation of Propan-2-one with Formaldehyde and Propane-2-thiol
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DOI: 10.1134/s1070363220040015
Abstract: Abstract Three-component condensation of propan-2-one with formaldehyde and propane-2-thiol in the presence of sodium hydroxide afforded 3-{[(propan-2-yl)sulfanyl)]methyl}but-3-en-2-one or 4-[(propan-2-yl)sulfanyl]-3-{[(propan-2-yl)sulfanyl]methyl}butan-2-one, depending on the amount of the base. The formation of 4-[(propan-2-yl)sulfanyl]-3-{[(propan-2-yl)sulfanyl]methyl}butan-2-one from 4-[(propan-2-yl)sulfanyl]butan-2-one involved aldol condensation… read more here.
Keywords: propan sulfanyl; sulfanyl; condensation; propane thiol ... See more keywords