Stereodivergent Synthesis of (Z)-/(E)-β-Sulfonylacrylamides via Tandem Difunctionalization of Alkynes with Sulfinates and Isocyanides.
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DOI: 10.1021/acs.orglett.2c03092
Abstract: Stereoselective difunctionalizations of the terminal and internal alkynes with various sulfinates and isocyanides have been achieved to prepare (Z)-/(E)-β-sulfonylacrylamides. The (Z)-β-sulfonylacrylamides were generated via a one-pot process that involves the reaction of terminal alkynes with… read more here.
Keywords: alkynes sulfinates; synthesis sulfonylacrylamides; sulfonylacrylamides via; sulfinates isocyanides ... See more keywords