Sulfonated N-heterocyclic carbine-silver (I) complexes: Synthesis, characterisation and biological evaluation
Sign Up to like & getrecommendations! Published in 2018 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.4016
Abstract: The synthesis, characterisation and biological activity of water-soluble Ag(I)-NHC complexes, general formula Na[(NHC)AgCl] where NHC is a sulfonated and sterically hindered N-heterocyclic carbene, is reported. The Ag-NHC complexes (2a–e) were synthesised by reacting the corresponding… read more here.
Keywords: heterocyclic carbine; characterisation biological; sulfonated heterocyclic; synthesis characterisation ... See more keywords
Aqueous-Phase Chemistry of η3-Allylpalladium(II) Complexes with Sulfonated N-Heterocyclic Carbene Ligands: Solvent Effects in the Protolysis of Pd–C Bonds and Suzuki–Miyaura Reactions
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00635
Abstract: The synthesis of water-soluble η3-allyl Pd(II) complexes containing sulfonated N-heterocyclic carbene (NHC) ligands of general formula [Pd(NHC)n(η3-allyl)Cl2–n] is reported (n = 1 (1) or 2 (8)). Monocarbene complexes were obtained with the most sterically hindered… read more here.
Keywords: water; chemistry; protolysis; sulfonated heterocyclic ... See more keywords