Articles with "sulfone" as a keyword



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Segmental dynamics of functional graphene‐filled poly(ether sulfone ether ketone ketone) nanocomposites

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Published in 2017 at "Journal of Applied Polymer Science"

DOI: 10.1002/app.44391

Abstract: The segmental dynamics of functional graphene (fGR)/poly(ether sulfone ether ketone ketone) (PESEKK) nanocomposites were investigated via differential scanning calorimetry and dynamic mechanical analysis (DMA) measurements. First, fGR was prepared using graphene oxide and sodium dodecylbenzene… read more here.

Keywords: pesekk; ether ketone; sulfone; pesekk nanocomposites ... See more keywords

Sulindac sulfone inhibits the mTORC1 pathway in colon cancer cells by directly targeting voltage-dependent anion channel 1 and 2.

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Published in 2018 at "Biochemical and biophysical research communications"

DOI: 10.1016/j.bbrc.2018.10.050

Abstract: Sulindac sulfone is a metabolite of sulindac, a non-steroidal anti-inflammatory drug (NSAID), without anti-inflammatory ability. However, sulindac sulfone has been reported to significantly reduce polyps in patients with colorectal adenomatous polyposis in clinical trials. Thus,… read more here.

Keywords: vdac1 vdac2; sulindac sulfone; sulfone; colon cancer ... See more keywords
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Adsorption of benzothiophene sulfone over clay mineral adsorbents in the frame of oxidative desulfurization

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Published in 2017 at "Fuel"

DOI: 10.1016/j.fuel.2017.05.070

Abstract: Abstract The adsorption of benzothiophene sulfone (BTO) from model fuel oil was investigated using three different clay mineral adsorbents. The adsorption characteristics of clay mineral adsorbents such as activated clay, bentonite and kaolinite were evaluated… read more here.

Keywords: clay mineral; adsorption; adsorption benzothiophene; sulfone ... See more keywords
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High performance blend membranes based on densely sulfonated poly(fluorenyl ether sulfone) block copolymer and imidazolium-functionalized poly(ether sulfone)

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Published in 2017 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2017.06.040

Abstract: Abstract Abstract Novel physically crosslinked polymer membranes were prepared by simply blending densely sulfonated poly(fluorenyl ether sulfone) with imidazolium-functionalized poly(ether sulfone). The blend showed well-defined ionic channels originating from the densely sulfonated structure and was… read more here.

Keywords: poly fluorenyl; fluorenyl ether; sulfone; ether sulfone ... See more keywords
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Solution-blended sulfonated polyphenylene and branched poly(arylene ether sulfone): Synthesis, state of water, surface energy, proton transport, and fuel cell performance

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Published in 2019 at "Polymer"

DOI: 10.1016/j.polymer.2018.11.045

Abstract: Abstract A poly(arylene ether sulfone) (PAES) was synthesized with a sulfonated poly(phenyl sulfone) side-chain (sB) to create a branched sBPAES ionomer. This sBPAES ionomer was solution blended with sulfonated polyphenylene (sPP). The sulfonated side-chain dramatically… read more here.

Keywords: water; proton; sbpaes; sulfone ... See more keywords
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Divergent synthesis of functionalized dihydropyridines and pyrroles via metal-free one-pot domino reactions of a gem-disubstituted propargyl amine and an alkynyl sulfone

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Published in 2021 at "Tetrahedron Letters"

DOI: 10.1016/j.tetlet.2021.153283

Abstract: Abstract Reaction of an 2-amino-2-ethynylmalonate derivative with an ethynyl sulfone allowed metal-free divergent synthesis of 1,6-dihydropyridines (DHPs) and 3,5-disubstituted pyrroles in one-pot. This facile atom-economical domino process involves hetero-conjugate addition and subsequent propargyl aza-Claisen-type rearrangement,… read more here.

Keywords: metal free; sulfone; divergent synthesis; one pot ... See more keywords
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Rapid Synthesis of the epi-Biotin Sulfone via Tandem S,N-Carbonyl Migration/aza-Michael/Spirocyclization and Haller–Bauer Reaction

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Published in 2022 at "ACS Omega"

DOI: 10.1021/acsomega.2c01030

Abstract: A synthesis of 2-epi-biotin sulfone was accomplished from commercially available l-cysteine. The synthesis features an unprecedented tandem S,N-carbonyl migration/aza-Michael/spirocyclization reaction from an l-cysteine-derived enone with aq. ammonia, in which three new sigma bonds and two… read more here.

Keywords: epi biotin; reaction; synthesis; sulfone ... See more keywords
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Pyrimidine Nucleosides with a Reactive (β-Chlorovinyl)sulfone or (β-Keto)sulfone Group at the C5 Position, Their Reactions with Nucleophiles and Electrophiles, and Their Polymerase-Catalyzed Incorporation into DNA

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Published in 2018 at "ACS Omega"

DOI: 10.1021/acsomega.8b00584

Abstract: Transition-metal-catalyzed chlorosulfonylation of 5-ethynylpyrimidine nucleosides provided (E)-5-(β-chlorovinyl)sulfones A, which undergo nucleophilic substitution with amines or thiols affording B. The treatment of vinyl sulfones A with ammonia followed by acid-catalyzed hydrolysis of the intermediary β-sulfonylvinylamines gave… read more here.

Keywords: nucleosides reactive; dna; sulfone; pyrimidine nucleosides ... See more keywords
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Anion exchange membranes by bromination of tetramethylbiphenol-based poly(sulfone)s

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Published in 2017 at "Polymer Chemistry"

DOI: 10.1039/c7py00026j

Abstract: Anion exchange membranes (AEM) with tunable properties were synthesized via bromination of poly(ether sulfone)s containing tetramethylbiphenol (TMBP) comonomers, followed by bromination, quaternization, and ion exchange. The bromination reactions of poly(ether sulfone)s containing TMBP and tetramethylbisphenol… read more here.

Keywords: bromination; anion exchange; based poly; sulfone ... See more keywords
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UV-crosslinked poly(arylene ether sulfone) – LAPONITE® nanocomposites for proton exchange membranes

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Published in 2017 at "RSC Advances"

DOI: 10.1039/c7ra04419d

Abstract: The dimensional stability and barrier properties of proton exchange membranes are critical issues for high-performance proton exchange membrane fuel cells (PEMFCs). In this work, we introduce a viable and effective strategy for preparing high proton-conductive… read more here.

Keywords: proton exchange; poly arylene; sulfone; exchange ... See more keywords
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Altered methionine-sulfone levels are associated with impaired growth in HEU-children.

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Published in 2023 at "AIDS"

DOI: 10.1097/qad.0000000000003574

Abstract: OBJECTIVE To determine immune-metabolic dysregulation in children born to women living with HIV. METHODS Longitudinal immune-metabolomic analyses of plasma of 32 pregnant women living with HIV (WLHIV) and 12 uninfected women and their children up… read more here.

Keywords: heu children; growth; methionine sulfone; sulfone ... See more keywords