A chemical kinetic model for the decomposition of perfluorinated sulfonic acids.
Sign Up to like & getrecommendations! Published in 2021 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2020.128256
Abstract: Perfluorinated sulfonic acids (such as perfluorooctanesulfonic, PFOS, and short-chain analogues) are notorious halogenated pollutants that exhibit severe toxicity, even at minute levels. Limited number of experimental studies addressed their thermal decomposition at elevated temperatures. Such… read more here.
Keywords: perfluorinated sulfonic; sulfonic acids; model; chemical kinetic ... See more keywords
Spontaneous Oxidation of Aromatic Sulfones to Sulfonic Acids in Microdroplets.
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DOI: 10.1021/jasms.2c00029
Abstract: Reactions in microdroplets can be accelerated and can present unique chemistry compared to reactions in bulk solution. Here, we report the accelerated oxidation of aromatic sulfones to sulfonic acids in microdroplets under ambient conditions without… read more here.
Keywords: oxidation aromatic; reaction; acids microdroplets; aromatic sulfones ... See more keywords
Design of (β-diazo-α,α-difluoroethyl)phosphonates and their application as masked carbenes in visible light-promoted coupling reactions with sulfonic acids
Sign Up to like & getrecommendations! Published in 2021 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo01394c
Abstract: We elaborate a method for the generation of (2-diazo-1,1-difluoroethyl)phosphonates from (β-amino-α,α-difluoroethyl)phosphonates as precursors and their application as masked carbenes in coupling reactions with sulfonic acids under photochemical conditions. Varieties of coupling partners including aminophosphonates and… read more here.
Keywords: application masked; masked carbenes; sulfonic acids; diazo difluoroethyl ... See more keywords