Transfer-catalyst-free biomimetic asymmetric reduction of 3-sulfonyl coumarins with a regenerable NAD(P)H model.
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DOI: 10.1039/d1cc06896b
Abstract: A novel transfer-catalyst-free biomimetic reduction of the tetrasubstituted olefins 3-sulfonyl coumarins with the chiral and regenerable [2.2]paracyclophane-based NAD(P)H model CYNAM has been developed, affording chiral 3-sulfonyl dihydrocoumarins with excellent enantioselectivities. read more here.
Keywords: free biomimetic; catalyst free; transfer catalyst; sulfonyl coumarins ... See more keywords