Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C–H Bonds
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DOI: 10.1021/acs.macromol.8b00134
Abstract: Aromatic sulfonyl halides are readily accessible from many sources. With newly synthesized N-arylphenothiazine catalysts, organocatalyzed photoredox polymerization has been developed with arylsulfonyl halides initiators using white or purple LEDs light sources. This method allows the… read more here.
Keywords: aromatic sulfonyl; photoredox polymerization; organocatalyzed photoredox; sulfonyl halides ... See more keywords
Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides
Sign Up to like & getrecommendations! Published in 2022 at "Organic Letters"
DOI: 10.1021/acs.orglett.2c01604
Abstract: Methanedisulfonyl fluoride, CH2(SO2F)2, transforms aromatic aldehydes into β-arylethenesulfonyl fluorides, useful substrates for the SuFEx “click”-type transformations. The reaction mimics mechanism of the Horner–Wadsworth–Emmons olefination, which runs via addition of the carbanion, followed by cyclization–fragmentation of… read more here.
Keywords: synthesis unsaturated; olefination sulfonyl; unsaturated sulfonyl; halides esters ... See more keywords