Iodine‐Mediated Sulfonylation of Quinoline N‐Oxides: a Mild and Metal‐Free One‐Pot Synthesis of 2‐Sulfonyl Quinolines
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DOI: 10.1002/ajoc.201700001
Abstract: A synthetic strategy for an iodine-mediated sulfonylation of quinoline N-oxides has been developed. A wide variety of 2-sulfonyl quinoline derivatives were synthesized by reacting various quinoline N-oxides with different sodium sulfinates in the presence of… read more here.
Keywords: quinoline oxides; mediated sulfonylation; iodine mediated; sulfonylation quinoline ... See more keywords
Copper-Catalyzed Deoxygenative C2-Sulfonylation of Quinoline N-Oxides with DABSO and Phenyldiazonium Tetrafluoroborates for the Synthesis of 2-Sulfonylquinolines via a Radical Reaction
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DOI: 10.1055/s-0037-1611787
Abstract: An efficient and practical method for the synthesis of 2-sulfonylquinolines through copper-catalyzed deoxygenative C2-sulfonylation of quinoline N-oxides with 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and phenyldiazonium tetrafluoroborates is demonstrated. Products with various substituents were obtained in moderate… read more here.
Keywords: quinoline oxides; deoxygenative sulfonylation; sulfonylation quinoline; catalyzed deoxygenative ... See more keywords