Kinetics of chromium(V)-oxo and chromium(IV)-oxo porphyrins: Reactivity and mechanism for sulfoxidation reactions.
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DOI: 10.2139/ssrn.4163383
Abstract: In this work, chromium(IV)-oxo porphyrins [CrIV(Por)(O)] (2) (Por = porphyrin) were produced either by oxidation of [CrIII(Por)Cl] (1) with iodobenzene diacetate or visible light photolysis of porphyrin‑chromium(III) chlorates. Subsequent oxidation of 2 with silver perchlorate gave chromium(V)-oxo… read more here.
Keywords: oxo; chromium oxo; oxo porphyrins; porphyrin ... See more keywords