Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications
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DOI: 10.1021/acscatal.0c00690
Abstract: The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir[(dF(CF3)ppy)2(dtbbpy)]PF6 or fac-Ir(ppy)3 is reported. Mechanistic studies indicate that a radical chain mechanism operates, which proceeds via a phosphoranyl radical generated from a radical/polar… read more here.
Keywords: photocatalytic deoxygenation; deoxygenation sulfoxides; using visible; sulfoxides using ... See more keywords