Electrophilic Sulfur Reagent Design Enables Directed syn-Carbosulfenylation of Unactivated Alkenes.
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DOI: 10.1021/jacs.1c13252
Abstract: A multi-component approach to structurally complex organosulfur products is described via the nickel-catalyzed 1,2-carbosulfenylation of unactivated alkenes with organoboron nucleophiles and tailored organosulfur electrophiles. The key to the development of this transformation is the identification… read more here.
Keywords: reagent design; electrophilic sulfur; sulfur reagent; carbosulfenylation unactivated ... See more keywords