New Chemical Transformations Involving SO2 F2 -Mediated Alcohol Activation.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical record"
DOI: 10.1002/tcr.202300107
Abstract: Sulfuryl fluoride is a gas produced on a multi-ton scale for its use as a fumigant. In the last decades, it has gained interest in organic synthesis as a reagent with unique properties in terms… read more here.
Keywords: sulfuryl fluoride; so2 mediated; transformations involving; chemical transformations ... See more keywords
Synthesis of Arenesulfonyl Fluorides via Sulfuryl Fluoride Incorporation from Arynes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.8b03610
Abstract: Transition-metal-free multicomponent reactions involving aryne precursors, secondary amines, and sulfuryl fluoride are reported herein. Zwitterionic intermediates formed from the reaction of arynes with amine nucleophiles can capture SO2F2 under mild conditions, offering a novel and… read more here.
Keywords: fluorides via; synthesis arenesulfonyl; via sulfuryl; fluoride incorporation ... See more keywords