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Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04856b
Abstract: Cu(II)-mediated C-H sulphenylation or selenylation of Trp indole by a derivative of cysteine or selenocysteine enables access to the tryptathionine unit or its selenium congener. The mechanism of these protocols, which allow macrocyclization of Trp-containing…
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Keywords:
mediated sulphenylation;
copper mediated;
macrocyclization;
sulphenylation selenylation ... See more keywords