Tuning the dielectric response by co-crystallisation of sumanene and its fluorinated derivative.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02766f
Abstract: A series of co-crystals of 1,1-difluorosumanene (F2-Sum) and sumanene (Sum) were obtained. The co-crystallization successfully tuned their structural and physical properties, especially the dielectric response, without any chemical modifications. X-ray analyses and theoretical calculations revealed… read more here.
Keywords: dielectric response; response crystallisation; crystallisation sumanene; sumanene ... See more keywords
Synthetic approaches to bowl-shaped π-conjugated sumanene and its congeners
Sign Up to like & getrecommendations! Published in 2020 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.16.186
Abstract: Since the first synthetic report in 2003 by Sakurai et al., sumanene (derived from the Indian ‘Hindi as well as Sanskrit word’ “Suman”, which means “Sunflower”), a beautifully simple yet much effective bowl-shaped C3-symmetric polycyclic… read more here.
Keywords: sumanene; chemistry; bowl; approaches bowl ... See more keywords