Reactivity of the Sulfur-Based Space Molecules CS2, COS, and HNCS in Superacidic Media.
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DOI: 10.1021/acs.inorgchem.5c01993
Abstract: The sulfur-based heteroallenes COS, CS2, and KSCN were investigated in binary superacidic media HF/L (L = BF3, AsF5, or SbF5) in order to isolate and characterize the protonated species, which are present in interstellar media.… read more here.
Keywords: sulfur based; molecules cs2; reactivity sulfur; superacidic media ... See more keywords
HF-Addition to Haloacetyl Fluorides in Superacidic Media
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DOI: 10.1039/d4nj02884h
Abstract: The reactions of difluoroacetyl fluoride and trifluoroacetyl fluoride were investigated in the binary superacid HF/SbF5 by low-temperature NMR spectroscopy. Whereas both haloacetyl fluorides form oxonium species after the addition of... read more here.
Keywords: haloacetyl fluorides; haloacetyl; addition haloacetyl; superacidic media ... See more keywords