Parity-forbidden superatomic molecular orbital interaction and aurophilicity induced H─Au bonding in H@Au20
Sign Up to like & getrecommendations! Published in 2025 at "Science Advances"
DOI: 10.1126/sciadv.adx2053
Abstract: Understanding H─Au interaction is essential for elucidating the stereochemistry and reactivity of gold hydrides. By embedding a hydrogen atom in the central tetrahedral cavity of Au20, we identify a distinct form of hydrogen-mediated bonding in… read more here.
Keywords: superatomic molecular; parity forbidden; forbidden superatomic; interaction ... See more keywords