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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c02098
Abstract: We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag17, prepared from chiral alkynyl ligands. R-Ag17 and S-Ag17 possess C3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under…
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Keywords:
silver clusters;
circularly polarized;
superatomic silver;
polarized luminescence ... See more keywords
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Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11338
Abstract: Convenient generation of stable superatomic silver clusters and their systematic site-specific tailoring and directional assembly present an enduring and significant challenge. In this work, we prepared a face-centered cubic (fcc) array of Ag14 superatoms protected…
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Keywords:
site specific;
superatomic silver;
tailoring directional;
specific tailoring ... See more keywords
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Published in 2023 at "Nanoscale"
DOI: 10.1039/d3nr00571b
Abstract: The first series of monocarboxylate-protected superatomic silver nanoclusters was synthesized and fully characterized by X-ray diffraction, fourier-transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and electrospray ionization mass spectrometry (ESI-MS). Specifically, compounds [Ag16(L)8(9-AnCO2)12]2+ (L =…
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Keywords:
superatomic silver;
spectroscopy;
monocarboxylate protected;
silver nanoclusters ... See more keywords