Rhodium catalysts with superbulky NHC ligands for the selective α-hydrothiolation of alkynes.
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DOI: 10.1039/d2dt00243d
Abstract: Eight rhodium complexes-including four new compounds-with the generic formula [RhCl(cod)(NHC)] (cod is 1,3-cyclooctadiene) differing by the size of their N-heterocyclic carbene (NHC) ligand were prepared, characterized, and found to be catalytically active in the hydrothiolation… read more here.
Keywords: ligands selective; rhodium catalysts; nhc ligands; hydrothiolation ... See more keywords