A path to design stronger superacids by using superhalogens
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2017.03.001
Abstract: Abstract Conjugate superacids consist of Bronsted/Lewis acid components, which can be designed by the protonation of superhalogen anions, the anions with larger vertical detachment energy (VDE) than halogens. The most stable superhalogen anions are composed… read more here.
Keywords: path design; superhalogen anions; design stronger; superhalogen ... See more keywords
Superhalogen Anions Supported by the Systems Comprising Alternately Aligned Boron and Nitrogen Central Atoms
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.863408
Abstract: Using DFT/(B3LYP/wB97XD/B2PLYPD) and OVGF electronic structure methods with flexible atomic orbital basis sets, we examined the series of polynuclear superhalogen anions matching the (BF3(BN) n F4n+1)– formula (for n = 1-10,13,18-20) containing alternately aligned boron… read more here.
Keywords: aligned boron; superhalogen anions; nitrogen central; alternately aligned ... See more keywords