A Polysiloxide Complex with two Chromium(III) η 2 ‐Superoxo Moieties
Sign Up to like & getrecommendations! Published in 2019 at "Israel Journal of Chemistry"
DOI: 10.1002/ijch.201900119
Abstract: The isolation and identification of intermediates formed in the course of the activation of dioxygen at transition metal centers reveals important mechanistic insights concerning such processes. We previously reported the reaction of the dinuclear Cr… read more here.
Keywords: superoxo; two chromium; polysiloxide complex; complex two ... See more keywords
End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10252
Abstract: In this report, we investigate the physical and chemical properties of monocopper Cu(I) superoxo and Cu(II) peroxo and hydroperoxo complexes. These are prepared by cryoreduction/annealing of the parent [LCuI(O2)]+ Cu(I) dioxygen adducts with the tripodal,… read more here.
Keywords: superoxo peroxo; spectroscopy; peroxo hydroperoxo; superoxo ... See more keywords
Structure and reactivity of the first-row d-block metal-superoxo complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01402k
Abstract: In the first-row of d-block metals, ten elements are included, such as scandium (Sc, 3d1), titanium (Ti, 3d2), vanadium (V, 3d3), chromium (Cr, 3d54s1), manganese (Mn, 3d5), iron (Fe, 3d6), cobalt (Co, 3d7), nickel (Ni,… read more here.
Keywords: superoxo; superoxo complexes; iii superoxo; first row ... See more keywords
How Do Quantum Chemical Descriptors Shape the Hydrogen Atom Abstraction Reactivity in Cupric-superoxo Species? A Combined DFT and Machine Learning Perspective
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d4qi00701h
Abstract: Oxygen activation, a crucial function performed by enzymes, prompts the synthesis of biomimetic models to investigate structure-activity relationships, with a particular focus on metal-superoxo species resulting from O2 interaction with... read more here.
Keywords: descriptors shape; shape hydrogen; chemical descriptors; superoxo ... See more keywords