Hydrogen Atom Abstraction Thermodynamics of a μ-1,2-Superoxo Dicopper(II) Complex.
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DOI: 10.1021/jacs.7b05722
Abstract: Pyrazolate-based μ-1,2-peroxo dicopper(II) complex 1 undergoes clean 1e- oxidation at low potential (-0.59 V vs Fc/Fc+) to yield the rather stable μ-1,2-superoxo dicopper(II) complex 3, which was characterized by spectroscopic methods (ν̃(O-O) = 1070 cm-1,… read more here.
Keywords: dicopper; atom abstraction; thermodynamics; superoxo dicopper ... See more keywords