Rational Design and Construction of Hierarchical Superstructures Using Shape-Persistent Organic Cages: Porphyrin Box-Based Metallosupramolecular Assemblies.
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DOI: 10.1021/jacs.8b08030
Abstract: We report a new approach to building hierarchical superstructures using a shape-persistent porous organic cage, which acts as a premade secondary building unit, and coordination chemistry. To illustrate the principle, a zinc-metalated porphyrin box (Zn-PB),… read more here.
Keywords: shape persistent; superstructures using; hierarchical superstructures; porphyrin box ... See more keywords