π-Carbazolyl supported bis(alkyl) complexes of Sc, Y and La for α-olefin polymerization and hydrogenation.
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DOI: 10.1039/d2dt01188c
Abstract: A series of new half-sandwich bis(alkyl) rare-earth metal complexes coordinated by a sterically demanding 1,3,6,8-tetra-tert-butyl-carbazol-9-yl ligand [tBu4Carb]La(CH2C6H5)2(THF) (1-La), [tBu4Carb]Ln(o-NMe2C6H4CH2)2 (Ln = Sc (2-Sc), Y (2-Y), La (2-La), [tBu4Carb]Ln(CH2SiMe3)2(THF) (Ln = Sc (3-Sc), Y (3-Y)), were… read more here.
Keywords: bis alkyl; alkyl; hydrogenation; supported bis ... See more keywords