High-Performance Supported Iridium Oxohydroxide Water Oxidation Electrocatalysts.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201601817
Abstract: The synthesis of a highly active and yet stable electrocatalyst for the anodic oxygen evolution reaction (OER) remains a major challenge for acidic water splitting on an industrial scale. To address this challenge, we obtained… read more here.
Keywords: water; supported iridium; performance supported; performance ... See more keywords
Development of titania-supported iridium catalysts with excellent low-temperature activities for the synthesis of benzimidazoles via hydrogen transfer
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2019.110550
Abstract: Abstract Titania-supported iridium catalysts which enable the synthesis of benzimidazoles from 2-nitroaniline and primary alcohols under mild conditions have been developed. The iridium catalysts supported on {010}/{101}-faceted anatase (PA-135-3.5) showed the excellent activity in spite… read more here.
Keywords: iridium catalysts; supported iridium; titania supported; synthesis benzimidazoles ... See more keywords
Poly(2,2'-Bibenzimidazole)-Supported Iridium Complex: A Recyclable Metal-Polymer Ligand Bifunctional Catalyst for the N-Methylation of Amines with Methanol.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c02053
Abstract: The design and development of new types of catalysts is one of the most important topics for modern chemistry. Herein, a polymer-supported iridium complex Cp*Ir@Poly(2,2'-BiBzIm) was designed and synthesized by the coordinative immobilization of [Cp*IrCl2]2… read more here.
Keywords: chemistry; catalyst; iridium complex; polymer ... See more keywords
Linear-Organic-Polymer-Supported Iridium Complex as a Recyclable Auto-Tandem Catalyst for the Synthesis of Quinazolinones via Selective Hydration/Acceptorless Dehydrogenative Coupling from o-Aminobenzonitriles.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00475
Abstract: A linear-organic-polymer-supported iridium complex Cp*Ir@P4VP, which is designed and synthesized by the coordinative immobilization of [Cp*IrCl2]2 on poly(4-vinylpyridine), was proven to be an efficient heterogeneous autotandem catalyst for synthesizing quinazolinones via selective hydration/acceptorless dehydrogenative coupling… read more here.
Keywords: iridium complex; organic polymer; supported iridium; polymer supported ... See more keywords
Site-Selective and Late-Stage Deuteration of (Hetero)arenes with Supported Iridium Nanoparticles
Sign Up to like & getrecommendations! Published in 2025 at "ACS Catalysis"
DOI: 10.1021/acscatal.4c07364
Abstract: : Deuterated compounds have emerged as critical tools across diverse research areas, including pharmaceuticals, where deuterium incorporation can modulate the absorption, distribution, metabolism, and excretion (ADME) properties of drugs. In this study, we report the… read more here.
Keywords: iridium nanoparticles; site; deuteration; supported iridium ... See more keywords
MgO-Supported Iridium Metal Pair-Site Catalysts Are More Active and Resistant to CO Poisoning than Analogous Single-Site Catalysts for Ethylene Hydrogenation and Hydrogen–Deuterium Exchange
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03463
Abstract: Atomically dispersed supported catalysts are drawing wide attention because they offer properties different from those of conventional catalysts, with maximally efficient use of the metals. However... read more here.
Keywords: iridium metal; mgo supported; metal pair; supported iridium ... See more keywords
Selective Hydrodeoxygenation of Lignin-Derived Phenols to Aromatics Catalyzed by Nb2O5-Supported Iridium
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04314
Abstract: The dominating catalytic approach to aromatic hydrocarbons from renewables, deoxygenation of phenol-rich depolymerized lignin bio-oils, is hard to achieve: hydrodeoxygenation (HDO) of phenols typically leads to the loss of aromaticity and to non-negligible fractions of… read more here.
Keywords: supported iridium; derived phenols; hydrodeoxygenation; lignin derived ... See more keywords
Supported Iridium Catalyst for the Green Synthesis of 3,3′-Bis(indolyl)methanes Using Methanol As the Bridging Methylene Source
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.9b00094
Abstract: The first example of a heterogeneous catalyst based on hydrotalcite-derived Mg–Al oxides supported iridium (Ir/MgxAlO) for activation of methanol in the synthesis of bis(indolyl)methanes (BIMs) is reported. In this clean and reusable iridium-based catalytic system,… read more here.
Keywords: synthesis; indolyl methanes; supported iridium; catalyst ... See more keywords
β-Diketiminate-supported iridium photosensitizers with increased excited-state reducing power
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry frontiers"
DOI: 10.1039/d1qi00382h
Abstract: A series of bis-cyclometalated iridium complexes were prepared which combine triazole or NHC-based cyclometalating ligands with substituted β-diketiminate (NacNac) ancillary ligands. The HOMO is localized on the NacNac ligand and its energy and associated redox… read more here.
Keywords: excited state; supported iridium; iridium photosensitizers; diketiminate supported ... See more keywords