Molecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysis.
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DOI: 10.1039/c8cc05152f
Abstract: Bis(triphenylsilyl) and dibenzyl ytterbium(ii) complexes supported by the macrocyclic polyamine ligand Me4TACD (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) reacted with H2 to give the cationic ytterbium hydrides [(Me4TACD)2Yb2(μ2-H)(2+n)](2-n)+ (n = 0, 1). The hydrides catalyzed the H2/D2 isotope exchange as… read more here.
Keywords: ytterbium; hydrides divalent; supported macrocyclic; divalent ytterbium ... See more keywords