A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01993a
Abstract: The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a redox-active dinucleating ligand. read more here.
Keywords: supported redox; complexes supported; versatile route; route homo ... See more keywords
Combined antioxidant capped and surface supported redox-sensitive nanoparticles for continuous elimination of multi-metallic species.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc02972j
Abstract: A strategic modification involving (i) a multi-functional almond shell biochar surface support and (ii) capping with almond skin extracted antioxidants was performed to preserve redox-sensitive Fe0 nanoparticles (NPs). pXRD data showed generation of an iron-carbonyl… read more here.
Keywords: combined antioxidant; supported redox; capped surface; redox sensitive ... See more keywords
C(sp2)–H Iodination by a Rhodium(III) Complex Supported by a Redox-active Ligand Bearing Amidophenolato Moieties
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry Letters"
DOI: 10.1246/cl.200178
Abstract: C(sp2)–H iodination of m-xylene promoted by a rhodium(III) complex supported by a redox-active ligand, (nBu4N)[RhIIIL3−(MeCN)Cl] (1Cl), is reported. The iodination reaction involves an electrophili... read more here.
Keywords: iodination; supported redox; complex supported; sp2 iodination ... See more keywords