A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry
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DOI: 10.1039/d3sc00808h
Abstract: Electron-deficient, anti-aromatic 2,5-disilyl boroles are shown to be a flexibly adaptive molecular platform with regards to SiMe3 mobility in their reaction with the nucleophilic donor-stabilised precursor dichloro silylene SiCl2(IDipp). Depending on the substitution pattern, selective… read more here.
Keywords: platform; donor supported; chemistry; supported silavinylidene ... See more keywords