Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand
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DOI: 10.1016/j.jorganchem.2017.12.032
Abstract: Abstract The sterically encumbered NacNac ligand, [HC(MeCNAr)2]− (Ar = 2,6-i-Pr2C6H3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal… read more here.
Keywords: supported sterically; functionalities supported; sterically encumbered; encumbered diketiminate ... See more keywords
Ferrous complexes supported by sterically encumbered asymmetric bis(arylimino)acenaphthene (BIAN) ligands: synthesis, characterization and screening for catalytic hydrosilylation of carbonyl compounds
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DOI: 10.1039/c7ra01511a
Abstract: Six ferrous chloride complexes ((Ar-BIANX)FeCl2: Ar = 2,6-diisopropylphenyl (Dipp), X = F (1), Cl (2), Me (3); Ar = mesityl (Mes), X = F (4), Cl (5), Me (6)) supported by sterically bulky asymmetric bis(arylimino)acenaphthene… read more here.
Keywords: bian ligands; bis arylimino; arylimino acenaphthene; acenaphthene bian ... See more keywords