Interpreting the Operando XANES of Surface-Supported Subnanometer Clusters: When Fluxionality, Oxidation State, and Size Effect Fight
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c02823
Abstract: X-ray absorption near edge structure (XANES) spectroscopy is widely used for operando catalyst characterization. We show that, for highly fluxional supported nanoclusters, the customary extraction ... read more here.
Keywords: subnanometer clusters; surface supported; supported subnanometer; operando xanes ... See more keywords
Low-Temperature Direct Oxidation of Propane to Propylene Oxide Using Supported Subnanometer Cu Clusters
Sign Up to like & getrecommendations! Published in 2025 at "ACS Catalysis"
DOI: 10.1021/acscatal.4c07577
Abstract: Propylene oxide, a key commodity of the chemical industry for a wide range of consumer products, is synthesized through sequential propane dehydrogenation and epoxidation reactions. However, the lack of a direct catalytic route from propane… read more here.
Keywords: propane propylene; propylene oxide; propylene; low temperature ... See more keywords