Chiroptical property tuning of supramolecular assemblies in polymer matrices.
Sign Up to like & getrecommendations! Published in 2020 at "Chirality"
DOI: 10.1002/chir.23201
Abstract: Chiroptical materials have received much attention in diverse fields for applications such as displays, sensors, smart memory devices, and catalysis. Here, we develop a simple fabrication method for polymer films with tunable chiroptical properties using… read more here.
Keywords: supramolecular assemblies; chiroptical property; assemblies polymer; polymer matrices ... See more keywords
A Paradigm Shift from 2D to 3D: Surface Supramolecular Assemblies and Their Electronic Properties Explored by Scanning Tunneling Microscopy and Spectroscopy.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202300413
Abstract: Exploring supramolecular architectures at surfaces plays an increasingly important role in contemporary science, especially for molecular electronics. A paradigm of research interest in this context is shifting from 2D to 3D that is expanding from… read more here.
Keywords: tunneling microscopy; spectroscopy; supramolecular assemblies; microscopy ... See more keywords
Metallo-supramolecular assemblies of dinuclear Zn(II) and Mn(II) secondary building units (SBUs) and a bent silicon dicarboxylate ligand
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.08.027
Abstract: Abstract Two metallo-supramolecular polymers {[Zn2(L)4(DMF)2]·0.8DMF}n (1) and {[Mn2L2(DMSO)4]·2DMSO}n (2) (H2L = bis(p-carboxyphenyl)diphenylsilane) have been synthetized by the reaction of Zn(NO3)2·6H2O and Mn(NO3)2·4H2O respectively, with the above mentioned acid as ligand under solvothermal conditions. Both coordination polymers were… read more here.
Keywords: supramolecular assemblies; secondary building; metallo supramolecular; dinuclear secondary ... See more keywords
Thermal aggregates of human mortalin and Hsp70-1A behave as supramolecular assemblies.
Sign Up to like & getrecommendations! Published in 2019 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2019.12.236
Abstract: The Hsp70 family of heat shock proteins plays a critical function in maintaining cellular homeostasis within various subcellular compartments. The human mitochondrial Hsp70 (HSPA9) has been associated with cellular death, senescence, cancer and neurodegenerative diseases,… read more here.
Keywords: supramolecular assemblies; hsp70; mortalin hsp70; human mortalin ... See more keywords
Dynamic Adaptive Two-Dimensional Supramolecular Assemblies for On-Demand Filtration
Sign Up to like & getrecommendations! Published in 2019 at "iScience"
DOI: 10.1016/j.isci.2019.07.007
Abstract: Summary The construction of synthetic two-dimensional (2D) materials designates a pathway to the versatile chemical functionality by spatial control. However, current 2D materials with intelligence of stimuli-responsibility and adaptiveness have been unfledged. The approach reported… read more here.
Keywords: adaptive two; supramolecular assemblies; demand filtration; two dimensional ... See more keywords
Photochromism of three supramolecular assemblies derived from benzenecarboxylate donors and viologen acceptors
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.01.014
Abstract: Abstract Based on 1,2,4,5-benzenetetracarboxylic acid (H4BTEC) and different viologen cations (MQ+ = 1-methyl-4,4′-bipyridinium cation; MV2+ = 1,1′-bis(methyl)-4,4′-bipyridinium dication; EV2+ = 1,1′-bis(ethyl)-4,4′-bipyridinium dication), three novel supramolecular assemblies [(H3O)(MQ)(H4BTEC)(H2BTEC)]·H2O (1), (H3O)(MV)0.5(BTEC)0.5 (2), (H3O)(EV)0.5(H2BTEC) (3), have been synthesized and structurally characterized with viologen cations… read more here.
Keywords: three supramolecular; derived benzenecarboxylate; photochromism three; assemblies derived ... See more keywords
Principles of Cation-π Interactions for Engineering Mussel-Inspired Functional Materials.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00068
Abstract: ConspectusSupramolecular assembly is commonly driven by noncovalent interactions (e.g., hydrogen bonding, electrostatic, hydrophobic, and aromatic interactions) and plays a predominant role in multidisciplinary research areas ranging from materials design to molecular biology. Understanding these noncovalent… read more here.
Keywords: mussel inspired; cation interactions; engineering; functional materials ... See more keywords
Engineering Long-Range Order in Supramolecular Assemblies on Surfaces: The Paramount Role of Internal Double Bonds in Discrete Long-Chain Naphthalenediimides
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c00765
Abstract: Achieving long-range order with surface-supported supramolecular assemblies is one of the pressing challenges in the prospering field of non-covalent surface functionalization. Having access to defect-free on-surface molecular assemblies will pave the way for various nanotechnology… read more here.
Keywords: supramolecular assemblies; internal double; range order; long range ... See more keywords
One-Step Synthesis of One-Dimensional Supramolecular Assemblies Composed of Helical Macromolecular Building Blocks.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b07417
Abstract: Living systems achieve sophisticated functions using supramolecular protein assemblies, in which the protein building blocks possess a specific secondary structure and are noncovalently arranged in a preprogrammed manner. Herein, we demonstrate the one-step synthesis of… read more here.
Keywords: supramolecular assemblies; synthesis one; building blocks; one dimensional ... See more keywords
Light-fueled transient supramolecular assemblies in water as fluorescence modulators
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-25299-8
Abstract: Dissipative self-assembly, which requires a continuous supply of fuel to maintain the assembled states far from equilibrium, is the foundation of biological systems. Among a variety of fuels, light, the original fuel of natural dissipative… read more here.
Keywords: supramolecular assemblies; transient supramolecular; water; dissipative self ... See more keywords
Highly selective absorption of polychloromethanes in perhydroxylated cucurbit[6]uril-based supramolecular assemblies
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03446f
Abstract: Two perhydroxylated cucurbit[6]uril-based supramolecular assemblies have been obtained via crystallization of perhydroxylated cucurbit[6]uril {(HO)12Q[6]} from aqueous HCl solutions of different concentrations. Single-crystal X-ray diffraction (unit cell) analysis revealed that (HO)12Q[6] molecules interacted with water molecules… read more here.
Keywords: supramolecular assemblies; perhydroxylated cucurbit; highly selective; cucurbit uril ... See more keywords