Construction of heterometallic M2Pd3 supramolecular cages via a metalloligand strategy as heterogeneous catalyst for Suzuki–Miyaura coupling reaction
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.07.009
Abstract: Abstract On the basis of hard soft acid base theory, two neutral heterometallic M2Pd3 supramolecular cages, [Al2Pd3(L)6Cl6] (1) and [Fe2Pd3(L)6Cl6] (2) (where HL is 1-(4-(1H-imidazol-1-yl)phenyl)butane-1,3-dione), have been constructed by using the tripodal M(L)3 as metalloligands… read more here.
Keywords: supramolecular cages; miyaura coupling; heterometallic m2pd3; m2pd3 supramolecular ... See more keywords
Reversible multi-electron storage in dual-site redox-active supramolecular cages.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc07138e
Abstract: M6L412+ supramolecular cages 3a and 3b (M = Pd, Pt), soluble in organic solvents, contain two different ligand-centered redox sites that enable the reversible storage of up to 16 electrons, as probed by CV, UV/vis… read more here.
Keywords: storage; supramolecular cages; reversible multi; multi electron ... See more keywords