Bioinorganic supramolecular coordination complexes and their biomedical applications
Sign Up to like & getrecommendations! Published in 2022 at "FEBS Letters"
DOI: 10.1002/1873-3468.14535
Abstract: The field of Bioinorganic Supramolecular Chemistry is an emerging research area including metal‐based supramolecules resulting from coordination‐driven self‐assembly (CDSA), whereby metal ions and organic ligands can be easily linked by metal–ligand bonds via Lewis' acid/base… read more here.
Keywords: coordination complexes; bioinorganic supramolecular; coordination; biomedical applications ... See more keywords
Two 3D Supramolecular Coordination Polymers Constructed from Aromatic Carboxylic Acids and Flexible Bis(thiabendazole) Ligands
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-017-0538-4
Abstract: Two coordination polymers (CPs), [Zn(L1)(H2bta)] (1) and [Co(L2)(ndc)]·0.75H2O (2), (L1 = 1,6-(thiabendazole)hexane), L2 = 1,3-(thiabendazole)propane, H4bta = 1,2,4,5-benzenetetracarboxylic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized. Single crystal X-ray diffraction analyses reveal that CP 1 and CP 2 feature 1D… read more here.
Keywords: coordination; supramolecular coordination; constructed aromatic; coordination polymers ... See more keywords
Single Crystal of New Nanostructure Self-Assembled Copper–Cyanide and Hexamethylenetetramine as an Efficient Supramolecular Coordination Polymer Catalyst
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-017-0749-8
Abstract: Yellow prismatic nanoparticles of the supramolecular coordination polymer (SCP) [Cu6(CN)7(C6H12N4)2(OH3)], 1 were obtained by the reaction of K3[Cu(CN)4] and hexamethylenetetramine (hmt) in presence of Me3SnCl at ambient conditions. The X-ray structure of 1 consists of… read more here.
Keywords: hexamethylenetetramine; catalyst; coordination polymer; supramolecular coordination ... See more keywords
STM probing the supramolecular coordination chemistry on solid surface: Structure, dynamic, and reactivity
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.01.014
Abstract: Abstract Supramolecular coordination chemistry is currently a very popular topic in metallorganic chemistry and has a very large impact on a broad field of applications. More importantly, the invention of STM has opened new doorways… read more here.
Keywords: coordination; surface; chemistry; supramolecular coordination ... See more keywords
Cd(II) supramolecular coordination polymer incorporating pyrazine-2-carboxylic acid: Crystal structure, spectral characteristics and catalytic activity
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.03.041
Abstract: Abstract Faint pink crystals of the supramolecular coordination polymer (SCP) {[Cd3(pyzca)6(H2O)4]·8H2O}, 1 were obtained by the reaction of cadmium sulfate with pyrazine-2-carboxylic acid (pyzcaH) as ligand. The structure of 1 was characterized by single crystal… read more here.
Keywords: pyrazine carboxylic; coordination polymer; carboxylic acid; supramolecular coordination ... See more keywords
Supramolecular coordination assemblies of 1,2,3-hexamethylcucurbit[5]uril with alkali metal ions based on the outer-surface interactions of cucurbit[n]urils
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.12.101
Abstract: Abstract Alkali cations (A+ = Na+, K+, Rb+, Cs+) were coordinated with 1,2,3-hexamethylcucurbit[5]uril (1,2,3-HMeQ[5]) using different structure directing agents. Single crystal X-ray diffraction revealed the formation of heterometallic molecular capsule-like complexes in the presence of [CdCl4]2− anions… read more here.
Keywords: supramolecular coordination; hexamethylcucurbit uril; structure directing; structure ... See more keywords
Syntheses and characterizations of copper(II)-supramolecular coordination compounds with 2,2-dimethylglutarate and diamine derivatives
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129097
Abstract: Abstract Three Copper(II) supramolecular coordination compounds (SCCs) named as {[Cu2(µ-dmglu)2(µ-H2O)(dmen)2]·H2O}n (1), [Cu2(µ-dmglu)2(deten)2]·2H2O (2) and [Cu(µ-dmglu)(dmpen)]2 (3), have been synthesized using 2,2-dimethylglutaric acid (H2dmglu) and three different bidentate diamine ligands (dmen= N,N-dimethylethylenediamine, deten= N,N-diethylethylenediamine and dmpen=… read more here.
Keywords: coordination compounds; characterizations copper; supramolecular coordination; syntheses characterizations ... See more keywords
Hierarchical Assemblies of Supramolecular Coordination Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.8b00233
Abstract: Hierarchical self-assembly (HAS) is a multilevel organization process that first assembles elementary molecular units into ordered secondary structures via noncovalent interactions, which further act as the building blocks to form more complex multifunctional superstructures at… read more here.
Keywords: coordination; hierarchical systems; hierarchical assemblies; supramolecular coordination ... See more keywords
Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b04653
Abstract: Chiral self-sorting has great potential for constructing new complex structures and determining chirality-dependent properties in multicomponent mixtures. However, it is still of great challenge to achieve high fidelity chiral self-discrimination. Besides, the researches on the… read more here.
Keywords: coordination; coordination networks; networks high; supramolecular coordination ... See more keywords
Steric Effect of a Capping Ligand on the Formation of Supramolecular Coordination Networks of Ni(II): Solid-State Entrapment of Cyclic Water Dimer
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c03065
Abstract: Supramolecular dimer of water is the simplest of the small water clusters [(H2O)n, n = 2–10]. During the course of our work on supramolecular coordination networks of three-component systems (divalent metal ion, tridentate capping ligand,… read more here.
Keywords: methyl; water; dimer; supramolecular coordination ... See more keywords
Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b03856
Abstract: Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex… read more here.
Keywords: coordination; framework; diamondoid supramolecular; supramolecular coordination ... See more keywords