Supramolecular isomorphic dodecanuclear cobalt clusters with the same metal shell but different core ligands.
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DOI: 10.1039/d2dt00915c
Abstract: In this work, we report two supramolecular isomorphic dodecanuclear cobalt complexes, [Co12(mtz)3(L)6(NO3)2(OH)(N3)3]·(OH)3 (1) and [Co12(mtz)3(L)6(NO3)2(OH)(N3)(OAc)]·(OH)4 (2), (Hmtz = 5-methyl-1H-tetrazole, H2L = 7,7'-(ethane-1,1-diyl) diquinolin-8-ol) crystallizing in the P̄ space group with the same unit cell parameters.… read more here.
Keywords: dodecanuclear cobalt; isomorphic dodecanuclear; metal shell; supramolecular isomorphic ... See more keywords