Living Supramolecular Polymerization of DNA.
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201800342
Abstract: Recently there have been notable synthetic successes in supramolecular polymerization. By contrast, it has long been known that DNA can undergo supramolecular polymerization (concatemerization). Concatemerization is a step-like polymerization and consequently suffers from broad molecular… read more here.
Keywords: supramolecular polymerization; polymerization; concatemerization; polymerization dna ... See more keywords
Modeling and Designing Particle-Regulated Amyloid-like Assembly of Synthetic Polypeptides in Aqueous Solution.
Sign Up to like & getrecommendations! Published in 2021 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.1c01230
Abstract: In cells, actin and tubulin polymerization is regulated by nucleation factors, which promote the nucleation and subsequent growth of protein filaments in a controlled manner. Mimicking this natural mechanism to control the supramolecular polymerization of… read more here.
Keywords: polymerization; amyloid like; nucleation factors; supramolecular polymerization ... See more keywords
Flipping Motion To Bias the Organized Supramolecular Polymerization of N-Heterotriangulenes
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.9b01653
Abstract: Synergistic experimental and theoretical studies have allowed the disentangling of the possible pathways for the supramolecular polymerization of a series of dicyanovinyl-bridged N-heterotriangulene (NHT) derivatives bearing benzamide units with achiral (1a) and chiral (1b,c) side… read more here.
Keywords: supramolecular polymerization; flipping motion; monomeric species; bias organized ... See more keywords
Modeling Supramolecular Polymerization: The Role of Steric Effects and Hydrophobic Interactions
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b01435
Abstract: We present a combined experimental–simulation study of self-assembly into one-dimensional filaments. Experimentally, we study amphiphilic AuI-metallopeptides in neutral aqueous media. Our model foc... read more here.
Keywords: steric effects; supramolecular polymerization; modeling supramolecular; role steric ... See more keywords
Chiral Hierarchical Architecture Induced by Confinement-Assisted Living Supramolecular Polymerization of Simple Achiral Molecules.
Sign Up to like & getrecommendations! Published in 2023 at "ACS nano"
DOI: 10.1021/acsnano.2c12063
Abstract: Chiral supramolecular assembly (CSA) based on achiral molecules has provided important clues to understand the origin of biological chirality. However, a simple achiral monomer faces the challenge of chiral stacking with the absence of a… read more here.
Keywords: achiral molecules; supramolecular polymerization; living supramolecular; simple achiral ... See more keywords
From Photoinduced Supramolecular Polymerization to Responsive Organogels
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c01802
Abstract: Controlling supramolecular polymerization by external stimuli holds great potential toward the development of responsive soft materials and manipulating self-assembly at the nanoscale. Photochemical switching offers the prospect of regulating the structure and properties of systems… read more here.
Keywords: supramolecular polymerization; polymerization; organic solvents; photoinduced supramolecular ... See more keywords
Mutual Monomer Orientation To Bias the Supramolecular Polymerization of [6]Helicenes and the Resulting Circularly Polarized Light and Spin Filtering Properties
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00556
Abstract: We report on the synthesis and self-assembly of 2,15- and 4,13-disubstituted carbo[6]helicenes 1 and 2 bearing 3,4,5-tridodecyloxybenzamide groups. The self-assembly of these [6]helicenes is strongly influenced by the substitution pattern in the helicene core that… read more here.
Keywords: polarized light; spin filtering; supramolecular polymerization; orientation ... See more keywords
Supramolecular Polymerization of a Photo-Fluttering Chiral Monomer: A Temporarily Suspendable Chain Growth by Light.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02176
Abstract: Using a photochemically fluttering thiophene-fused cyclooctatetraene derivative (COT) as a nonplanar chiral monomer, we have succeeded in remotely suspending the supramolecular polymerization in a temporal manner by a completely new strategy. The COT monomer with… read more here.
Keywords: supramolecular polymerization; elongation; cot; chiral monomer ... See more keywords
Peptide Sequence Determines Structural Sensitivity to Supramolecular Polymerization Pathways and Bioactivity.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05759
Abstract: Pathways in supramolecular polymerization traverse different regions of the system's energy landscape, affecting not only their architectures and internal structure but also their functions. We report here on the effects of pathway selection on polymerization… read more here.
Keywords: internal structure; supramolecular polymerization; structure; sensitivity supramolecular ... See more keywords
Molecular Engineering of the Kinetic Barrier in Seeded Supramolecular Polymerization
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10482
Abstract: Seeded supramolecular polymerization (SSP) is a method that enables the controlled synthesis of supramolecular structures. SSP often relies on structures that are capable of self-assembly by interconverting between intramolecular and intermolecular modes of hydrogen bonding,… read more here.
Keywords: seeded supramolecular; supramolecular polymerization; hydrogen; kinetic barrier ... See more keywords
Pathway-Controlled Aqueous Supramolecular Polymerization via Solvent-Dependent Chain Conformation Effects.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12442
Abstract: Solute-solvent interactions play a critical role in multiple fields, including biology, materials science, and (physical) organic, polymer, and supramolecular chemistry. Within the growing field of supramolecular polymer science, these interactions have been recognized as an… read more here.
Keywords: conformation effects; supramolecular polymerization; chain conformation; aqueous supramolecular ... See more keywords