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   Articles with "surface synthesis" as a keyword



On‐Surface Synthesis of Organolanthanide Sandwich Complexes

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recommendations! Published in 2024 at "Advanced Science"

DOI: 10.1002/advs.202308125

Abstract: The synthesis of lanthanide‐based organometallic sandwich compounds is very appealing regarding their potential for single‐molecule magnetism. Here, it is exploited by on‐surface synthesis to design unprecedented lanthanide‐directed organometallic sandwich complexes on Au(111). The reported compounds… read more here.

Keywords: spectroscopy; surface synthesis; synthesis; synthesis organolanthanide ... See more keywords
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Preparation of Tetrabenzo[4.4.2]undecastarphene by On-Surface Synthesis.

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recommendations! Published in 2021 at "ChemPlusChem"

DOI: 10.1002/cplu.202100112

Abstract: A large dissymmetric starphene molecule, the tetrabenzo[a,c,u,w]naphtho[2,3-l]nonaphene, was obtained by first preparing a soluble precursor which was then sublimated on a Au(111) surface in an ultra-high vacuum. In a second step, controlled annealings from 200 °C… read more here.

Keywords: undecastarphene surface; tetrabenzo; surface; preparation tetrabenzo ... See more keywords

On Surface Synthesis of Sp‐Hybridized Carbon Allotropes

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recommendations! Published in 2025 at "Small Methods"

DOI: 10.1002/smtd.202500119

Abstract: Carbon allotropes have been extensively studied due to their unique structures and properties. Carbon exists in three hybridization states, among which sp‐hybridized carbon allotropes are particularly challenging to synthesize due to their high reactivity. On‐surface… read more here.

Keywords: carbon; synthesis hybridized; surface synthesis; hybridized carbon ... See more keywords

On-Surface Synthesis and Characterization of an Iron Corrole

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recommendations! Published in 2018 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.8b00067

Abstract: To explore the possibility of tuning the oxidation state of a coordinated metal ion in an adsorbed tetrapyrrole complex by a minor modification of the ligand structure, multilayers and monolayers of 3H-hexaethyl-dimethyl-corrole (3H-HEDMC) on Ag(111)… read more here.

Keywords: surface synthesis; spectroscopy; iron corrole; corrole ... See more keywords

On-Surface Synthesis of C144 Hexagonal Coronoid with Zigzag Edges.

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recommendations! Published in 2022 at "ACS nano"

DOI: 10.1021/acsnano.2c02163

Abstract: Coronoids as polycyclic aromatic macrocycles enclosing a cavity have attracted a lot of attention due to their distinctive molecular and electronic structures. They can be also regarded as nanoporous graphene molecules whose electronic properties are… read more here.

Keywords: synthesis c144; surface synthesis; hexagonal coronoid; zigzag edges ... See more keywords

On-Surface Synthesis of a Carbon Nanoribbon Composed of 4-5-6-8-Membered Rings.

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recommendations! Published in 2023 at "ACS nano"

DOI: 10.1021/acsnano.3c01915

Abstract: From the structure point of view, there are a number of ways of tiling a carbon sheet with different polygons, resulting in prospects of tailoring electronic structures of low-dimensional carbon nanomaterials. However, up to now,… read more here.

Keywords: nanoribbon composed; surface synthesis; carbon; membered rings ... See more keywords

On-Surface Synthesis of Polyene-Linked Porphyrin Cooligomer.

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recommendations! Published in 2024 at "ACS nano"

DOI: 10.1021/acsnano.3c12849

Abstract: π-Conjugated molecules are viewed as fundamental components in forthcoming molecular nanoelectronics in which semiconducting functional units are linked to each other via metallic molecular wires. However, it is still challenging to construct such block cooligomers… read more here.

Keywords: linked porphyrin; synthesis polyene; polyene linked; surface synthesis ... See more keywords

On-Surface Synthesis and Cryogenic Exfoliation of Sterically Frustrated Atropisomers

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recommendations! Published in 2025 at "ACS Nano"

DOI: 10.1021/acsnano.4c16645

Abstract: On-surface synthesis provides exceptional control over nanostructure and material composition, enabling the creation of molecular compounds that are difficult or impossible to obtain with other synthesis methods. In this work, we demonstrate the possibility of… read more here.

Keywords: surface synthesis; surface; synthesis; synthesis cryogenic ... See more keywords

Designing Optoelectronic Properties by On-Surface Synthesis: Formation and Electronic Structure of an Iron-Terpyridine Macromolecular Complex.

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recommendations! Published in 2018 at "ACS nano"

DOI: 10.1021/acsnano.8b01026

Abstract: Supramolecular chemistry protocols applied on surfaces offer compelling avenues for atomic-scale control over organic-inorganic interface structures. In this approach, adsorbate-surface interactions and two-dimensional confinement can lead to morphologies and properties that differ dramatically from those… read more here.

Keywords: iron terpyridine; electronic structure; optoelectronic properties; chemistry ... See more keywords

On-Surface Synthesis of Oligo(indenoindene).

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recommendations! Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.0c05701

Abstract: Fully conjugated ladder polymers (CLP) possess unique optical and electronic properties, and are considered promis-ing materials for applications in (opto)electronic devices. Poly(indenoindene) is a CLP consisting of an alternating array of five- and six-membered rings,… read more here.

Keywords: surface synthesis; oligo indenoindene; synthesis oligo; microscopy ... See more keywords

Selecting the Reaction Path in On-Surface Synthesis through the Electron Chemical Potential in Graphene.

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recommendations! Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c04359

Abstract: The organometallic on-surface synthesis of the eight-membered sp2 carbon-based ring cyclooctatetraene (C8H8, Cot) with the neighboring rare-earth elements ytterbium and thulium yields fundamentally different products for the two lanthanides, when conducted on graphene (Gr) close… read more here.

Keywords: surface synthesis; reaction; synthesis; electron chemical ... See more keywords