Enamines as Surrogates of Alkene Carbanions for the Reductive Alkenylation of Secondary Amides: An Approach to Allylamines.
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DOI: 10.1021/acs.orglett.7b03943
Abstract: A new strategy to construct allylamines through reductive alkenylation of secondary amides with enamines is reported. The method features the use of trifluoromethanesulfonic anhydride as an activation reagent of amides, and enamines as unconventional alkenylation… read more here.
Keywords: reductive alkenylation; alkenylation secondary; secondary amides; surrogates alkene ... See more keywords