A novel, C2-symmetric, chiral bis-cyclosulfinamide-olefin tridentate ligand in Rh-catalyzed asymmetric 1,4-additions
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DOI: 10.1016/j.tetlet.2018.06.008
Abstract: Abstract A C2-symmetric, chiral bis-cyclosulfinamide-olefin ligand composed of two 1-oxo-2,3-dihydro-1,2-benzisothiazole moieties with rigid skeletons and a conformationally flexible butenylene chain is disclosed for the first time. HRMS and 1H NMR analyses verify that the in… read more here.
Keywords: cyclosulfinamide olefin; symmetric chiral; chiral bis; tridentate ligand ... See more keywords