Palladium-catalysed α-allylation of chiral sulfinimines derived from symmetric cyclic ketones
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.02.008
Abstract: Abstract A diastereoselective mono-allylation reaction at the α-position of symmetric cyclic ketones by using tert-butanesulfinamide as a chiral auxiliary is explored. Excellent yields and high diastereomeric ratios were achieved under palladium(0) catalysis in the presence… read more here.
Keywords: symmetric cyclic; catalysed allylation; allylation chiral; cyclic ketones ... See more keywords