C2-Symmetric Hindered “Sandwich” Chiral N-Heterocyclic Carbene Precursors and Their Transition Metal Complexes: Expedient Syntheses, Structural Authentication, and Catalytic Properties
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DOI: 10.1021/acs.organomet.8b00492
Abstract: We present here a new family of C2-symmetric “sandwich” NHC ligands abbreviated as SITLAr and BzITLAr and their complexes. The chiral fragments incorporate bulky yet flexible cyclohexyl groups with α-stereocenters joined to nitrogens individually, which… read more here.
Keywords: sandwich chiral; hindered sandwich; carbene; symmetric hindered ... See more keywords