Stereoselective total synthesis of C2-symmetric natural products pyrenophorol and its derivatives
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DOI: 10.1080/14786419.2019.1577843
Abstract: Abstract A stereoselective total synthesis of 16-membered C2-symmetric macrodiolide Pyrenophorol, Tetrahydropyrenophorol and 4,4-diacetylpyrenophorol have been accomplished. The synthesis started from commercially available L-Aspartic acid and the key reactions involved are regioselective epoxide opening, CBS reduction,… read more here.
Keywords: synthesis symmetric; stereoselective total; natural products; symmetric natural ... See more keywords