Synthesis, structural investigation and antibacterial studies of non–symmetrically p–nitrobenzyl substituted benzimidazole N–heterocyclic carbene–silver(I) complexes
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DOI: 10.1016/j.ica.2017.06.072
Abstract: Abstract Several new non–symmetrically p–nitrobenzyl substituted benzimidazole–based mono–N–heterocyclic carbene (NHC)–silver(I) acetate (7a–e) and bis–NHC–silver(I) hexafluorophosphate complexes (8a–e) were synthesized by combination of 1–ethyl/1–propyl/1–butyl/1–pentyl/1–hexyl–3–(4–nitrobenzyl)benzimidazolium hexafluorophosphate salts (6a–e) with silver(I) acetate and silver(I) oxide in methanol and… read more here.
Keywords: symmetrically nitrobenzyl; non symmetrically; hexafluorophosphate; silver complexes ... See more keywords
Non-symmetrically p-nitrobenzyl- and p-cyanobenzyl-substituted N-heterocyclic carbene-silver(I) complexes: synthesis, characterization and antibacterial studies
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DOI: 10.1080/00958972.2016.1276574
Abstract: Abstract Various nitro/nitrile-functionalized benzimidazol-2-ylidene carbene complexes of silver(I) (7a–d and 11a–d) were synthesized by combination of 1-allyl/1-isopropyl/1-sec-butyl/1-isopentyl-3-(nitro/cyano-benzyl)-3H-benzimidazol-1-ium hexafluorophosphate (6a–d and 10a–d) with silver(I) oxide in acetonitrile. The compounds were characterized by 1H, 13C NMR, FT-IR,… read more here.
Keywords: symmetrically nitrobenzyl; non symmetrically; silver complexes; silver ... See more keywords