Synergetic Spin-Crossover and Luminescent Properties in a Multifunctional 2D Iron(II) Coordination Polymer.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03350
Abstract: We designed and synthesized a strong fluorescent tetradentate pyridine ligand, 3,6,11,12-tetra(pyridin-4-yl)dibenzo[a,c]phenazine (TPDP), by covalently grafting pyridyl to fluorescent dye dbpz, which can react with the Fe(NCX)2 (X = S and Se) unit, obtaining two new… read more here.
Keywords: luminescent properties; spin; synergetic spin; spin crossover ... See more keywords
Synergetic Spin-Valence Catalysis Mechanism in Oxygen Reduction Reactions on Fe-N-C Single-Atom Catalysts
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Materials Chemistry A"
DOI: 10.1039/d3ta00555k
Abstract: The spin and valence states of active sites have a direct and crucial bearing on the activity of transition-metal-based catalysts. However, modulating spin and valence states based on the synergistic... read more here.
Keywords: valence catalysis; spin valence; catalysis mechanism; synergetic spin ... See more keywords