Influence of the bite natural angle of bidentate diphosphine ligands in the syngas-free branched hydroformylation of β-functionalized olefins
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DOI: 10.1016/j.catcom.2018.08.007
Abstract: Abstract The correlation between the activity, regio- and chemoselectivity of Rh-diphosphine catalyst and the ligand bite natural angle (βn) in the syngas-free hydroformylation of allyl cyanide was investigated. A screening of Xantphos type and diphosphine… read more here.
Keywords: diphosphine ligands; bite natural; syngas free; natural angle ... See more keywords