Rare azido and hydroxido bridged tetranuclear Co(II) complexes of a polynucleating Mannich base ligand with a defect dicubane core: structures, magnetism and phenoxazinone synthase like activity
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DOI: 10.1039/c8nj04750b
Abstract: Three novel tetranuclear cobalt(II) complexes [Co4L2(μ1,1,1-N3)2(N3)2] (1), [Co4L2(μ3-OH)2(NCS)2]·4CH3CN (2) and [Co4L2(μ3-OH)2(NCSe)2]·2CH3CN (3) have been synthesized on reacting a Mannich base ligand, N,N′-dimethyl-N,N′-bis(2-hydroxy-3-methoxy-5-methylbenzyl)ethylenediamine (H2L), with cobalt(II) acetate tetrahydrate in the presence of azide, thiocyanate and selenocynate… read more here.
Keywords: mannich base; synthase like; base ligand; activity ... See more keywords
Synthesis, structure and phenoxazinone synthase-like activity of three unprecedented alternating CoII–CoIII 1D chains
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DOI: 10.1039/c9nj03236c
Abstract: Three new one-dimensional CoII/CoIII chains have been synthesized using N-salicylidene-l-alanine/N-salicylidene-l-phenylalanine and 2,2′-bipyridine/1,10-phenanthroline. All three complexes exhibit phenoxazinone synthase-like activity. read more here.
Keywords: coiii chains; like activity; synthase like; coii coiii ... See more keywords
Intragenic complementation at the Lotus japonicus CELLULOSE SYNTHASE-LIKE D1 locus rescues root hair defects.
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DOI: 10.1093/plphys/kiab204
Abstract: Root hair cells form the primary interface of plants with the soil environment, playing key roles in nutrient uptake and plant defense. In legumes, they are typically the first cells to become infected by nitrogen-fixing… read more here.
Keywords: synthase like; lotus japonicus; root hair; cellulose synthase ... See more keywords